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    Isobutene
    CAS No.: 115-11-7 Formula: C4H8 Molecular Weight: 56.10630
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    Isobutene

    CAS No.: 115-11-7 Formula: C4H8 Molecular Weight: 56.10630
    Suppliers: All (33) China Suppliers (33) Price Available (4) Contractor (3)

    Description

    Isobutylene (or 2-methylpropene) is a hydrocarbon of industrial significance. It is a four-carbon branched alkene (olefin), one of the four isomers of butylene. At standard temperature and pressure it is a colorless flammable gas.

    Basic Info

    Chemical Name Isobutene
    Synonyms

    Methylpropene; 1-Propene,2-methyl; 1-PROPENE, 2-METHYL-; 2-Methyl-1-propene; 2-Methylpropene; ISOBUTENE; ISOBUTYLENE; Propene,2-methyl; 2-methylprop-1-ene; 2-Methylpropylene; Expand

    CAS No. 115-11-7
    Molecular Formula C4H8
    Molecular Weight 56.10630
    PSA 0.00000
    LogP 1.58240

    Numbering system

    MDL number MFCD00008898
    RTECS number UD0890000
    PubChem number 24857786
    BRN number 773645
    EINECS number 204-066-3

    Properties

    Appearance & Physical State COLOURLESS COMPRESSED LIQUEFIED GAS , WITH CHARACTERISTIC ODOUR.
    Density 0.627 g/cm3
    Boiling Point -6.9oC(lit.)
    Melting Point -140oC
    Freezing Point -140.34℃
    Flash Point -80oC
    Refractive Index 1.3811
    Stability Stable. Highly flammable - readily forms an explosive mixture with air. Incompatible with strong oxidizing agents.
    Vapor Density 2 (vs air)
    Vapor Pressure 3278 mm Hg ( 37.7 °C)

    Safety Info

    RTECS UD0890000
    Hazard Class 2.1
    Safety Statements S9-S16-S33
    HS Code 2901233000
    WGK Germany -
    RIDADR UN 1055
    Risk Statements R12
    Hazard Codes F+
    SDS 1.0 Expand

    SDS 1.0

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    SAFETY DATA SHEETS

    According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

    Version: 1.0

    Creation Date: Aug 10, 2017

    Revision Date: Aug 10, 2017

    1.Identification

    1.1 GHS Product identifier

    Product name Isobutene

    1.2 Other means of identification

    Product number -
    Other names Propene,2-methyl

    1.3 Recommended use of the chemical and restrictions on use

    Identified uses For industry use only. Adhesives and sealant chemicals,Fuels and fuel additives,Intermediates,Lubricants and lubricant additives,Solvents (which become part of product formulation or mixture)
    Uses advised against no data available

    1.4 Supplier's details

    Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
    Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
    Xuhui District, Shanghai, China
    Telephone +86(21)64956998
    Fax +86(21)54365166

    1.5 Emergency phone number

    Emergency phone number +86-400-6021-666
    Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

    2.Hazard identification

    2.1 Classification of the substance or mixture

    Gases under pressure: Compressed gas

    Flammable gases, Category 1

    2.2 GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Danger

    Hazard statement(s)

    H220 Extremely flammable gas

    Precautionary statement(s)
    Prevention

    P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

    Response

    P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.

    P381 In case of leakage, eliminate all ignition sources.

    Storage

    P410+P403 Protect from sunlight. Store in a well-ventilated place.

    P403 Store in a well-ventilated place.

    Disposal

    none

    2.3 Other hazards which do not result in classification

    none

    3.Composition/information on ingredients

    3.1 Substances

    Chemical name Common names and synonyms CAS number EC number Concentration
    Isobutene Isobutene 115-11-7 none 100%

    4.First-aid measures

    4.1 Description of necessary first-aid measures

    General advice

    Consult a physician. Show this safety data sheet to the doctor in attendance.

    If inhaled

    Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.

    In case of skin contact

    ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention .

    In case of eye contact

    First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

    If swallowed

    Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

    4.2 Most important symptoms/effects, acute and delayed

    Inhalation of moderate concentrations causes dizziness, drowsiness, and unconsciousness. Contact with eyes or skin may cause irritation; the liquid may cause frostbite. (USCG, 1999)

    4.3 Indication of immediate medical attention and special treatment needed, if necessary

    Basic Treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... Anticipate seizures and treat as necessary ... For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... Treat frostbite with rapid rewarming techniques ... /Aliphatic hydrocarbons and related compounds/

    5.Fire-fighting measures

    5.1 Extinguishing media

    Suitable extinguishing media

    To fight fire, stop flow of gas.

    5.2 Specific hazards arising from the chemical

    Behavior in Fire: Containers may explode in fire. Vapor is heavier than air and may travel a long distance to a source of ignition and flash back. (USCG, 1999)

    5.3 Special protective actions for fire-fighters

    Wear self-contained breathing apparatus for firefighting if necessary.

    6.Accidental release measures

    6.1 Personal precautions, protective equipment and emergency procedures

    Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

    6.2 Environmental precautions

    Evacuate danger area! Consult an expert! Ventilation. Remove all ignition sources. Do NOT wash away into sewer. NEVER direct water jet on liquid. Personal protection: chemical protection suit including self-contained breathing apparatus.

    6.3 Methods and materials for containment and cleaning up

    Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

    7.Handling and storage

    7.1 Precautions for safe handling

    Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

    7.2 Conditions for safe storage, including any incompatibilities

    Fireproof. Separated from incompatible materials. See Chemical Dangers. Cool.... MATERIALS WHICH ARE TOXIC AS STORED OR WHICH CAN DECOMPOSE INTO TOXIC COMPONENTS ... SHOULD BE STORED IN A COOL, WELL VENTILATED PLACE, OUT OF THE DIRECT RAYS OF THE SUN, AWAY FROM AREAS OF HIGH FIRE HAZARD, AND SHOULD BE PERIODICALLY INSPECTED. INCOMPATIBLE MATERIALS SHOULD BE ISOLATED ...

    8.Exposure controls/personal protection

    8.1 Control parameters

    Occupational Exposure limit values

    no data available

    Biological limit values

    no data available

    8.2 Appropriate engineering controls

    Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

    8.3 Individual protection measures, such as personal protective equipment (PPE)

    Eye/face protection

    Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

    Skin protection

    Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

    Respiratory protection

    Wear dust mask when handling large quantities.

    Thermal hazards

    no data available

    9.Physical and chemical properties

    Physical state COLOURLESS COMPRESSED LIQUEFIED GAS , WITH CHARACTERISTIC ODOUR.
    Colour Easily liquefied gas
    Odour Coal gas odor
    Melting point/ freezing point 204°C(lit.)
    Boiling point or initial boiling point and boiling range 164°C/7mmHg(lit.)
    Flammability Extremely flammable.
    Lower and upper explosion limit / flammability limit no data available
    Flash point 101°C(lit.)
    Auto-ignition temperature 465°C (USCG, 1999)
    Decomposition temperature no data available
    pH no data available
    Kinematic viscosity no data available
    Solubility Insoluble
    Partition coefficient n-octanol/water (log value) log Kow = 2.34
    Vapour pressure 3278 mm Hg ( 37.7 °C)
    Density and/or relative density 0.627 g/cm3
    Relative vapour density 2 (vs air)
    Particle characteristics no data available

    10.Stability and reactivity

    10.1 Reactivity

    no data available

    10.2 Chemical stability

    VOLATILE LIQUID OR EASILY LIQUEFIED GAS.

    10.3 Possibility of hazardous reactions

    A very dangerous fire and explosion hazard when exposed to heat or flame.The gas is heavier than air and may travel along the ground; distant ignition possible. The gas is heavier than air and may accumulate in lowered spaces causing a deficiency of oxygen. As a result of flow, agitation, etc., electrostatic charges can be generated.ISOBUTYLENE is incompatible with oxidizers. It polymerizes easily. It reacts easily with numerous materials, such as alkyl halides, halogens, concentrated sulfuric acid, hypochlorous acid, aluminum chloride, carbon monoxide and hydrogen with a cobalt catalyst. Polymerization is catalyzed by aluminum chloride and boron trifluoride.

    10.4 Conditions to avoid

    no data available

    10.5 Incompatible materials

    CAN REACT VIGOROUSLY WITH OXIDIZING MATERIALS.

    10.6 Hazardous decomposition products

    When heated to decomposition it emits acrid smoke and fumes.

    11.Toxicological information

    Acute toxicity

    • Oral: LC50 Mouse oral 415 mg/L/2 hr
    • Inhalation: no data available
    • Dermal: no data available

    Skin corrosion/irritation

    no data available

    Serious eye damage/irritation

    no data available

    Respiratory or skin sensitization

    no data available

    Germ cell mutagenicity

    no data available

    Carcinogenicity

    no data available

    Reproductive toxicity

    no data available

    STOT-single exposure

    no data available

    STOT-repeated exposure

    no data available

    Aspiration hazard

    no data available

    12.Ecological information

    12.1 Toxicity

    • Toxicity to fish: no data available
    • Toxicity to daphnia and other aquatic invertebrates: no data available
    • Toxicity to algae: no data available
    • Toxicity to microorganisms: no data available

    12.2 Persistence and degradability

    Isobutylene was degraded to 1,2-epoxybutane by pure cultures of methanotrophic bacteria(1).

    12.3 Bioaccumulative potential

    An estimated BCF of 35 was calculated for isobutylene(SRC), using a log Kow of 2.34(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is moderate(SRC).

    12.4 Mobility in soil

    The Koc of isobutylene is estimated as 450(SRC), using a log Kow of 2.34(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that isobutylene is expected to have moderate mobility in soil(SRC).

    12.5 Other adverse effects

    no data available

    13.Disposal considerations

    13.1 Disposal methods

    Product

    The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

    Contaminated packaging

    Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

    14.Transport information

    14.1 UN Number

    ADR/RID: UN1993 IMDG: UN1993 IATA: UN1993

    14.2 UN Proper Shipping Name

    ADR/RID: FLAMMABLE LIQUID, N.O.S.
    IMDG: FLAMMABLE LIQUID, N.O.S.
    IATA: FLAMMABLE LIQUID, N.O.S.

    14.3 Transport hazard class(es)

    ADR/RID: 3 IMDG: 3 IATA: 3

    14.4 Packing group, if applicable

    ADR/RID: II IMDG: II IATA: II

    14.5 Environmental hazards

    ADR/RID: no IMDG: no IATA: no

    14.6 Special precautions for user

    no data available

    14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

    no data available

    15.Regulatory information

    15.1 Safety, health and environmental regulations specific for the product in question

    Chemical name Common names and synonyms CAS number EC number
    Isobutene Isobutene 115-11-7 none
    European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
    EC Inventory Listed.
    United States Toxic Substances Control Act (TSCA) Inventory Listed.
    China Catalog of Hazardous chemicals 2015 Listed.
    New Zealand Inventory of Chemicals (NZIoC) Listed.
    Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
    Vietnam National Chemical Inventory Listed.
    Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

    16.Other information

    Information on revision

    Creation Date Aug 10, 2017
    Revision Date Aug 10, 2017

    Abbreviations and acronyms

    • CAS: Chemical Abstracts Service
    • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
    • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
    • IMDG: International Maritime Dangerous Goods
    • IATA: International Air Transportation Association
    • TWA: Time Weighted Average
    • STEL: Short term exposure limit
    • LC50: Lethal Concentration 50%
    • LD50: Lethal Dose 50%
    • EC50: Effective Concentration 50%

    References

    • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
    • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
    • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
    • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
    • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
    • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
    • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
    • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
    • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

    Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
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