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    1-decene
    CAS No.: 872-05-9 Formula: C10H20 Molecular Weight: 140.26600
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    1-decene

    CAS No.: 872-05-9 Formula: C10H20 Molecular Weight: 140.26600
    Suppliers: All (25) China Suppliers (25) Price Available (6) Contractor(0)

    Description

    Decene is an alkene with the formula C 10H 20. Decene contains a chain of ten carbon atoms with one double bond. There are many isomers of decene depending on the position and geometry of the double bond. 1-Decene is the only isomer of industrial importance. As an alpha olefin, it is used as a monomer in copolymers and is an intermediate in the production of epoxides, amines, oxo alcohols, synthetic lubricants, synthetic fatty acids, and alkylated aromatics.
    The industrial processes used in the production of 1-decene are oligomerization of ethylene by the Ziegler Process or by the cracking of petrochemical waxes.
    1-Decene has been isolated from the leaves and rhizome of the plant Farfugium japonicum and has been detected as the initial product in the microbial degradation of n-decane.

    Numbering system

    MDL number MFCD00009577
    EINECS number 212-819-2

    Properties

    Appearance & Physical State clear, colorless liquid
    Density 0.741
    Boiling Point 169-171oC
    Melting Point -66.3oC
    Flash Point 49oC
    Refractive Index 1.42-1.422
    Water Solubility insoluble
    Stability Stable. Incompatible with strong oxidizing agents. Flammable.
    Storage Condition Flammables area
    Vapor Density 4.84 (vs air)
    Vapor Pressure 1.6 mm Hg ( 23.8 °C)

    Safety Info

    RTECS HE2071401
    Hazard Class 3
    Safety Statements S16-S37-S62
    HS Code 29012980
    WGK Germany 1
    Packing Group III
    RIDADR UN 3295
    Risk Statements R10; R38; R65
    Hazard Codes Xn
    SDS 1.0 Expand

    SDS 1.0

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    SAFETY DATA SHEETS

    According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

    Version: 1.0

    Creation Date: Aug 12, 2017

    Revision Date: Aug 12, 2017

    1.Identification

    1.1 GHS Product identifier

    Product name 1-decene

    1.2 Other means of identification

    Product number -
    Other names rac-(2R*)-2-(Benzoylamino)-4-methylvaleric acid

    1.3 Recommended use of the chemical and restrictions on use

    Identified uses For industry use only. Lubricants and lubricant additives
    Uses advised against no data available

    1.4 Supplier's details

    Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
    Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
    Xuhui District, Shanghai, China
    Telephone +86(21)64956998
    Fax +86(21)54365166

    1.5 Emergency phone number

    Emergency phone number +86-400-6021-666
    Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

    2.Hazard identification

    2.1 Classification of the substance or mixture

    Flammable liquids, Category 3

    Aspiration hazard, Category 1

    Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1

    2.2 GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Danger

    Hazard statement(s)

    H226 Flammable liquid and vapour

    H304 May be fatal if swallowed and enters airways

    H400 Very toxic to aquatic life

    H410 Very toxic to aquatic life with long lasting effects

    Precautionary statement(s)
    Prevention

    P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

    P233 Keep container tightly closed.

    P240 Ground and bond container and receiving equipment.

    P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment.

    P242 Use non-sparking tools.

    P243 Take action to prevent static discharges.

    P280 Wear protective gloves/protective clothing/eye protection/face protection.

    P273 Avoid release to the environment.

    Response

    P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

    P370+P378 In case of fire: Use ... to extinguish.

    P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/…

    P331 Do NOT induce vomiting.

    P391 Collect spillage.

    Storage

    P403+P235 Store in a well-ventilated place. Keep cool.

    P405 Store locked up.

    Disposal

    P501 Dispose of contents/container to ...

    2.3 Other hazards which do not result in classification

    none

    3.Composition/information on ingredients

    3.1 Substances

    Chemical name Common names and synonyms CAS number EC number Concentration
    1-decene 1-decene 872-05-9 none 100%

    4.First-aid measures

    4.1 Description of necessary first-aid measures

    General advice

    Consult a physician. Show this safety data sheet to the doctor in attendance.

    If inhaled

    Fresh air, rest.

    In case of skin contact

    Rinse skin with plenty of water or shower.

    In case of eye contact

    First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

    If swallowed

    Rinse mouth. Do NOT induce vomiting.

    4.2 Most important symptoms/effects, acute and delayed

    Vapors may produce slight irritation of eyes and respiratory tract if present in high concentration. May also act as a slight anesthetic at high concentration. (USCG, 1999)

    4.3 Indication of immediate medical attention and special treatment needed, if necessary

    no data available

    5.Fire-fighting measures

    5.1 Extinguishing media

    Suitable extinguishing media

    EXTINGUISH WITH DRY CHEMICAL, FOAM OR CARBON DIOXIDE.

    5.2 Specific hazards arising from the chemical

    Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. Substance may be transported hot. For hybrid vehicles, ERG Guide 147 (lithium ion batteries) or ERG Guide 138 (sodium batteries) should also be consulted. If molten aluminum is involved, refer to ERG Guide 169. (ERG, 2016)

    5.3 Special protective actions for fire-fighters

    Wear self-contained breathing apparatus for firefighting if necessary.

    6.Accidental release measures

    6.1 Personal precautions, protective equipment and emergency procedures

    Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

    6.2 Environmental precautions

    Remove all ignition sources. Personal protection: filter respirator for organic gases and particulates adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

    6.3 Methods and materials for containment and cleaning up

    Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

    7.Handling and storage

    7.1 Precautions for safe handling

    Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

    7.2 Conditions for safe storage, including any incompatibilities

    Fireproof. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access.

    8.Exposure controls/personal protection

    8.1 Control parameters

    Occupational Exposure limit values

    no data available

    Biological limit values

    no data available

    8.2 Appropriate engineering controls

    Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

    8.3 Individual protection measures, such as personal protective equipment (PPE)

    Eye/face protection

    Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

    Skin protection

    Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

    Respiratory protection

    Wear dust mask when handling large quantities.

    Thermal hazards

    no data available

    9.Physical and chemical properties

    Physical state clear, colorless liquid
    Colour Colorless liquid
    Odour PLEASANT
    Melting point/ freezing point -66°C(lit.)
    Boiling point or initial boiling point and boiling range 171°C(lit.)
    Flammability Flammable.
    Lower and upper explosion limit / flammability limit no data available
    Flash point 46°C(lit.)
    Auto-ignition temperature 235°C (USCG, 1999)
    Decomposition temperature no data available
    pH no data available
    Kinematic viscosity 1.09 sq mm/sec @ 20°C
    Solubility In water:insoluble
    Partition coefficient n-octanol/water (log value) log Kow= 5.70
    Vapour pressure 1.6 mm Hg ( 23.8 °C)
    Density and/or relative density 0.741
    Relative vapour density 4.84 (vs air)
    Particle characteristics no data available

    10.Stability and reactivity

    10.1 Reactivity

    no data available

    10.2 Chemical stability

    Stable under recommended storage conditions.

    10.3 Possibility of hazardous reactions

    As a result of flow, agitation, etc., electrostatic charges can be generated.As a result of flow, agitation, etc., electrostatic charges can be generated.1-DECENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions. Will attack some forms of plastics (USCG, 1999).

    10.4 Conditions to avoid

    no data available

    10.5 Incompatible materials

    no data available

    10.6 Hazardous decomposition products

    no data available

    11.Toxicological information

    Acute toxicity

    • Oral: no data available
    • Inhalation: no data available
    • Dermal: no data available

    Skin corrosion/irritation

    no data available

    Serious eye damage/irritation

    no data available

    Respiratory or skin sensitization

    no data available

    Germ cell mutagenicity

    no data available

    Carcinogenicity

    no data available

    Reproductive toxicity

    no data available

    STOT-single exposure

    no data available

    STOT-repeated exposure

    no data available

    Aspiration hazard

    no data available

    12.Ecological information

    12.1 Toxicity

    • Toxicity to fish: no data available
    • Toxicity to daphnia and other aquatic invertebrates: no data available
    • Toxicity to algae: no data available
    • Toxicity to microorganisms: no data available

    12.2 Persistence and degradability

    In a study of the degradation of hydrocarbons by various yeast cultures, 1-decene was assimilated by two out of thirteen cultures studied, Candida lipolytica and Candida pulcherrima(1). In a similar study of the yeast species Candida, 1-decene was found to be assimilated by 15 out of 55 Candid yeast cultures with only 2 of these displaying abundant growth, 8 moderate growth, and 5 slight growth(2). 1-Decene's linear hydrocarbon structure would suggest that biodegradation is an important process in soil and water(3).

    12.3 Bioaccumulative potential

    An estimated BCF of 488 was calculated for 1-decene(SRC), using a log Kow of 5.70(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is high.

    12.4 Mobility in soil

    Using a structure estimation method based on molecular connectivity indices(1), the Koc for 1-decene can be estimated to be about 1720(SRC). According to a classification scheme(2), this estimated Koc value suggests that 1-decene is expected to have low mobility in soil.

    12.5 Other adverse effects

    no data available

    13.Disposal considerations

    13.1 Disposal methods

    Product

    The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

    Contaminated packaging

    Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

    14.Transport information

    14.1 UN Number

    ADR/RID: UN3295 IMDG: UN3295 IATA: UN3295

    14.2 UN Proper Shipping Name

    ADR/RID: HYDROCARBONS, LIQUID, N.O.S.
    IMDG: HYDROCARBONS, LIQUID, N.O.S.
    IATA: HYDROCARBONS, LIQUID, N.O.S.

    14.3 Transport hazard class(es)

    ADR/RID: 3 IMDG: 3 IATA: 3

    14.4 Packing group, if applicable

    ADR/RID: III IMDG: III IATA: III

    14.5 Environmental hazards

    ADR/RID: yes IMDG: yes IATA: yes

    14.6 Special precautions for user

    no data available

    14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

    no data available

    15.Regulatory information

    15.1 Safety, health and environmental regulations specific for the product in question

    Chemical name Common names and synonyms CAS number EC number
    1-decene 1-decene 872-05-9 none
    European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
    EC Inventory Listed.
    United States Toxic Substances Control Act (TSCA) Inventory Listed.
    China Catalog of Hazardous chemicals 2015 Listed.
    New Zealand Inventory of Chemicals (NZIoC) Listed.
    Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
    Vietnam National Chemical Inventory Not Listed.
    Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

    16.Other information

    Information on revision

    Creation Date Aug 12, 2017
    Revision Date Aug 12, 2017

    Abbreviations and acronyms

    • CAS: Chemical Abstracts Service
    • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
    • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
    • IMDG: International Maritime Dangerous Goods
    • IATA: International Air Transportation Association
    • TWA: Time Weighted Average
    • STEL: Short term exposure limit
    • LC50: Lethal Concentration 50%
    • LD50: Lethal Dose 50%
    • EC50: Effective Concentration 50%

    References

    • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
    • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
    • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
    • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
    • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
    • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
    • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
    • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
    • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

    Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
    MSDS Expand
    1H NMR : 90 MHz in CDCl3Expand

    NMR Spectrum 1H NMR : 90 MHz in CDCl3

    Collapse

    C10 H20 0.04 ml : 0.5 ml CDCl3
    1-decene

    Assign. Shift(ppm)
    A 5.79
    B 4.98
    C 4.92
    D 2.03
    E 1.41
    F 1.28
    G 0.89

    IR : liquid filmExpand
    Mass Expand
    Raman : 4880 A,100M,liquidExpand
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