• <xmp id="gswu8"><nav id="gswu8"></nav>
  • <nav id="gswu8"><strong id="gswu8"></strong></nav><nav id="gswu8"></nav>
    Ethylene glycol
    CAS No.: 107-21-1 Formula: C2H6O2 Molecular Weight: 62.06780
    Search Suppliers

    Ethylene glycol

    CAS No.: 107-21-1 Formula: C2H6O2 Molecular Weight: 62.06780
    Suppliers: All (378) China Suppliers (290) Price Available (55) Contractor (32)

    Description

    Ethylene glycol (IUPAC name: ethane-1,2-diol) is an organic compound with the formula (CH2OH)2. It is mainly used for two purposes, as a raw material in the manufacture of polyester fibers and for antifreeze formulations. It is an odorless, colorless, sweet-tasting syrup. Ethylene glycol is moderately toxic.

    Basic Info

    Chemical Name Ethylene glycol
    Synonyms

    1,2-dihydroxy ethane; Ethane-1,2-diol; 1,2-Ethanediol; 1,2-Dihydroxyethane; 2-hydroxy ethanol;

    CAS No. 107-21-1
    Molecular Formula C2H6O2
    Molecular Weight 62.06780
    PSA 40.46000
    LogP -1.02900

    Numbering system

    MDL number MFCD00283324
    EINECS number 203-473-3
    RTECS number KW2975000
    BRN number 505945
    PubChem number 24859450

    Properties

    Appearance & Physical State clear viscous liquid
    Density 1.220 g/mL at 25oC
    Boiling Point 196-198oC
    Melting Point -13oC
    Freezing Point -11.5℃
    Flash Point 116oC
    Refractive Index 1.43-1.433
    Water Solubility miscible
    Stability Stable at room temperature in closed containers under normal storage and handling conditions.
    Storage Condition 2-8oC
    Vapor Density 2.1 (vs air)
    Vapor Pressure 0.08 mm Hg ( 20 °C)

    Safety Info

    RTECS KW2975000
    Safety Statements S26
    HS Code 2905310000
    WGK Germany 3
    RIDADR UN 1219 3/PG 2
    Risk Statements R22
    Hazard Codes Xn
    Symbol GHS07, GHS08
    Caution Statement P260; P301 + P312 + P330
    Signal Word Warning
    Hazard Declaration H302; H373
    SDS 1.0 Expand

    SDS 1.0

    Collapse
    Download/Modify | Technical supported by XiXisys.com. For US version, EU version (23 languages) and more, please refer to xixisys.com/en/sds/search

    SAFETY DATA SHEETS

    According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

    Version: 1.0

    Creation Date: Aug 10, 2017

    Revision Date: Aug 10, 2017

    1.Identification

    1.1 GHS Product identifier

    Product name Ethylene glycol

    1.2 Other means of identification

    Product number -
    Other names 1,2-dihydroxy ethane

    1.3 Recommended use of the chemical and restrictions on use

    Identified uses For industry use only. Ethylene glycol is used as antifreeze in cooling and heating systems, in hydraulic brake fluids, as an industrial humectant, as an ingredient of electrolytic condensers, as a solvent in the paint and plastics industries, in the formulations of printers' inks, stamp pad inks, and inks for ballpoint pens, as a softening agent for cellophane, and in the synthesis of safety explosives, plasticizers, synthetic fibers (Terylene, Dacron), and synthetic waxes. Ethylene glycol is also used to de-ice airport runways and aircraft. (2)
    Uses advised against no data available

    1.4 Supplier's details

    Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
    Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
    Xuhui District, Shanghai, China
    Telephone +86(21)64956998
    Fax +86(21)54365166

    1.5 Emergency phone number

    Emergency phone number +86-400-6021-666
    Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

    2.Hazard identification

    2.1 Classification of the substance or mixture

    Acute toxicity - Oral, Category 4

    2.2 GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Warning

    Hazard statement(s)

    H302 Harmful if swallowed

    Precautionary statement(s)
    Prevention

    P264 Wash ... thoroughly after handling.

    P270 Do not eat, drink or smoke when using this product.

    Response

    P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/…if you feel unwell.

    P330 Rinse mouth.

    Storage

    none

    Disposal

    P501 Dispose of contents/container to ...

    2.3 Other hazards which do not result in classification

    none

    3.Composition/information on ingredients

    3.1 Substances

    Chemical name Common names and synonyms CAS number EC number Concentration
    Ethylene glycol Ethylene glycol 107-21-1 none 100%

    4.First-aid measures

    4.1 Description of necessary first-aid measures

    General advice

    Consult a physician. Show this safety data sheet to the doctor in attendance.

    If inhaled

    Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.

    In case of skin contact

    Remove contaminated clothes. Rinse skin with plenty of water or shower.

    In case of eye contact

    First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

    If swallowed

    Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention .

    4.2 Most important symptoms/effects, acute and delayed

    Inhalation of vapor is not hazardous. Ingestion causes stupor or coma, sometimes leading to fatal kidney injury. (USCG, 1999)

    4.3 Indication of immediate medical attention and special treatment needed, if necessary

    /SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Ethylene glycol, glycols, and related compounds/

    5.Fire-fighting measures

    5.1 Extinguishing media

    Suitable extinguishing media

    In case of fire in the surroundings: carbon dioxide, foam, powder, water spray.

    5.2 Specific hazards arising from the chemical

    This chemical is combustible.

    5.3 Special protective actions for fire-fighters

    Wear self-contained breathing apparatus for firefighting if necessary.

    6.Accidental release measures

    6.1 Personal precautions, protective equipment and emergency procedures

    Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

    6.2 Environmental precautions

    Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in sealable containers as far as possible. Wash away remainder with plenty of water.

    6.3 Methods and materials for containment and cleaning up

    Collect leaking liquid in covered containers. Wash away spilled liquid with plenty of water.

    7.Handling and storage

    7.1 Precautions for safe handling

    Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

    7.2 Conditions for safe storage, including any incompatibilities

    Separated from strong oxidants and strong bases. Dry. Ventilation along the floor.Polyethylene glycols should be stored in well-closed containers in a cool, dry place. Stainless steel, aluminum, glass, or lined steel containers are preferred for the storage of liquid grades.

    8.Exposure controls/personal protection

    8.1 Control parameters

    Occupational Exposure limit values

    no data available

    Biological limit values

    no data available

    8.2 Appropriate engineering controls

    Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

    8.3 Individual protection measures, such as personal protective equipment (PPE)

    Eye/face protection

    Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

    Skin protection

    Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

    Respiratory protection

    Wear dust mask when handling large quantities.

    Thermal hazards

    no data available

    9.Physical and chemical properties

    Physical state clear viscous liquid
    Colour Clear, colorless, viscous liquids to waxy solids
    Odour no data available
    Melting point/ freezing point -13°C(lit.)
    Boiling point or initial boiling point and boiling range 195-198°C
    Flammability Combustible.
    Lower and upper explosion limit / flammability limit no data available
    Flash point 111°C
    Auto-ignition temperature 400°C
    Decomposition temperature no data available
    pH no data available
    Kinematic viscosity /p>PEG 400: 105 to 130 mPa.s at 20?°C; PEG 3000: 75 to 100 mPa.s at 20?°C; PEG 3350: 83 to 120 mPa.s at 20?°C; PEG 4000: 110 to 170 mPa.s at 20?°C; PEG 6000: 200 to 270 mPa.s at 20?°C; PEG 8000: 260 to 510 mPa.s at 20?°C; For polyethylene glycols having a average molecular weight greater than 400, the viscosity is determined on a 50 per cent m/m solution of the candidate substance in water
    Solubility In water:miscible
    Partition coefficient n-octanol/water (log value) -1.93
    Vapour pressure 0.08 mm Hg ( 20 °C)
    Density and/or relative density 1.113g/mLat 25°C(lit.)
    Relative vapour density 2.1 (vs air)
    Particle characteristics no data available

    10.Stability and reactivity

    10.1 Reactivity

    no data available

    10.2 Chemical stability

    Polyethylene glycols are chemically stable in air and in solution, although grades with a mol wt < 2000 are hygroscopic. Polyethylene glycols do not support microbial growth, and they do not become rancid. Polyethylene glycols and aqueous polyethylene glycol solutions can be sterilized by autoclaving, filtration, or gamma irradiation ... Ideally, sterilization should be carried out in an inert atmosphere.

    10.3 Possibility of hazardous reactions

    CombustibleVapors are heavier than air and will collect and stay in poorly-ventilated, low-lying, or confined areas (e.g., sewers, basements, and tanks).Hazardous concentrations may develop quickly in enclosed, poorly-ventilated, or low-lying areas. Keep out of these areas. Stay upwind.Mixing ETHYLENE GLYCOL in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid, oleum, sulfuric acid, [NFPA 1991].

    10.4 Conditions to avoid

    no data available

    10.5 Incompatible materials

    Materials to avoid: Strong oxidizing agents.

    10.6 Hazardous decomposition products

    When heated to decomposition it emits acrid smoke and irritating fumes.

    11.Toxicological information

    Acute toxicity

    • Oral: Animal toxicity data for Polyethylene glycols (see Table) LD50 mg/kg PEG grade Guinea pig (oral) Mouse (ip) Mouse (iv) Mouse (oral) Rabbit (oral) Rabbit (iv) Rat (ip) Rat (iv) Rat (oral) 200 --- 7500 --- 3400 19900 --- --- --- 28000 300 19600 --- --- 17300 --- --- --- --- 27500 400 15700 10000 8600 28900 26800 --- 9700 7300 --- 600 --- --- --- 47000 --- --- --- --- 38100 1000 --- 20000 --- --- --- --- 15600 --- 44200 1500 28900 --- --- --- 28900 8000 17700 --- 44200 4000 50900 --- 16000 --- 76000 --- 11600 --- 50000 6000 50000 --- --- --- --- --- 6800 --- ---
    • Inhalation: no data available
    • Dermal: no data available

    Skin corrosion/irritation

    no data available

    Serious eye damage/irritation

    no data available

    Respiratory or skin sensitization

    no data available

    Germ cell mutagenicity

    no data available

    Carcinogenicity

    TLV-A4

    Reproductive toxicity

    No information is available on the reproductive or developmental effects of ethylene glycol in humans. Several studies of rodents exposed orally or by inhalation showed ethylene glycol to affect animal fetuses. Fetotoxicity manifested as increased preimplantation loss, delayed ossification, and an increased incidence of fetal malformations were reported. The inhalation study, however, noted continuous grooming of the fur, resulting in a high rate of exposure by ingestion as well.

    STOT-single exposure

    no data available

    STOT-repeated exposure

    no data available

    Aspiration hazard

    no data available

    12.Ecological information

    12.1 Toxicity

    • Toxicity to fish: LC50; Species: Oncorhynchus mykiss (Rainbow trout, weight 25-50 g); Conditions: freshwater, static, 14°C, pH 7.2, dissolved oxygen 10 mg/L; Concentration: >20000000 ug/L for 96 hr /PEG400
    • Toxicity to daphnia and other aquatic invertebrates: no data available
    • Toxicity to algae: no data available
    • Toxicity to microorganisms: no data available

    12.2 Persistence and degradability

    ... will not support mold growth

    12.3 Bioaccumulative potential

    no data available

    12.4 Mobility in soil

    no data available

    12.5 Other adverse effects

    no data available

    13.Disposal considerations

    13.1 Disposal methods

    Product

    The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

    Contaminated packaging

    Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

    14.Transport information

    14.1 UN Number

    ADR/RID: UN3082 IMDG: UN3082 IATA: UN3082

    14.2 UN Proper Shipping Name

    ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
    IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
    IATA: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

    14.3 Transport hazard class(es)

    ADR/RID: 9 IMDG: 9 IATA: 9

    14.4 Packing group, if applicable

    ADR/RID: III IMDG: III IATA: III

    14.5 Environmental hazards

    ADR/RID: no IMDG: no IATA: no

    14.6 Special precautions for user

    no data available

    14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

    no data available

    15.Regulatory information

    15.1 Safety, health and environmental regulations specific for the product in question

    Chemical name Common names and synonyms CAS number EC number
    Ethylene glycol Ethylene glycol 107-21-1 none
    European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
    EC Inventory Listed.
    United States Toxic Substances Control Act (TSCA) Inventory Listed.
    China Catalog of Hazardous chemicals 2015 Not Listed.
    New Zealand Inventory of Chemicals (NZIoC) Listed.
    Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
    Vietnam National Chemical Inventory Listed.
    Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

    16.Other information

    Information on revision

    Creation Date Aug 10, 2017
    Revision Date Aug 10, 2017

    Abbreviations and acronyms

    • CAS: Chemical Abstracts Service
    • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
    • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
    • IMDG: International Maritime Dangerous Goods
    • IATA: International Air Transportation Association
    • TWA: Time Weighted Average
    • STEL: Short term exposure limit
    • LC50: Lethal Concentration 50%
    • LD50: Lethal Dose 50%
    • EC50: Effective Concentration 50%

    References

    • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
    • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
    • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
    • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
    • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
    • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
    • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
    • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
    • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

    Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
    MSDS Expand
    1H NMR : in CDCl3Expand

    NMR Spectrum 1H NMR : in CDCl3

    Collapse

    C2H6O2 0.019 g : 0.5 ml CDCl3
    1,2-ethanediol

    Assign. Shift(ppm)
    A 3.716
    B 3.17

    Assigned with HMQC and HMBC.

    IR : liquid filmExpand
    Mass Expand
    Raman : 4880 A,150M,liquidExpand

    GC Analysis

    Total 19 Documents >>
    Column type Active phase Temperature (°C) Retention Index (I) Temperature Control Method
    Packed SE-30 150. 705. isothermal
    Packed Apiezon L 160. 659. isothermal
    Packed PEG-2000 179. 1695. isothermal
    Packed PEG-2000 180. 1652. isothermal
    Packed PEG-2000 200. 1667. isothermal
    Recommended Suppliers
    More Suppliers>>
    Other items you might be interested in
    Category in MOLBASE
    天天干夜夜操