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    75-09-2 structure, CH2Cl2
    dichloromethane
    CAS No.: 75-09-2 Formula: CH2Cl2 Molecular Weight: 84.93260
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    dichloromethane

    CAS No.:

    75-09-2

    Formula:

    CH2Cl2

    Molecular Weight: 84.93260
    Suppliers: All (158) China Suppliers (158) Price Available (26) Contractor (17)

    Description

    Dichloromethane (DCM, or methylene chloride) is an organic compound with the formula CH2Cl2. This colorless, volatile liquid with a moderately sweet aroma is widely used as a solvent. Although it is not miscible with water, it is miscible with many organic solvents. One of the most well-known applications of dichloromethane is in the drinking bird heat engine.

    Basic Info

    Chemical Name

    dichloromethane

    Synonyms

    Methane,dichloro; Solmethine; Methane dichloride; methylene chloride; Dichloromethane; Methane, dichloro-; Solaesthin; Freon 30; methylene dichloride; Methylene bichloride; Expand

    CAS No.

    75-09-2

    Molecular Formula

    CH2Cl2

    Molecular Weight

    84.93260

    PSA

    0.00000

    LogP

    1.42150

    Numbering system

    UNII 588X2YUY0A

    Properties

    Appearance & Physical State

    A colorless liquid with a sweet, penetrating, ether-like odor

    Density

    1.325

    Boiling Point

    39-40oC

    Melting Point

    -97oC

    Flash Point

    39-40oC

    Refractive Index

    1.4242

    Water Solubility

    20 g/L (20 oC)

    Storage Condition

    Store at RT.

    Vapor Density

    2.9 (vs air)

    Vapor Pressure

    24.45 psi ( 55 °C)

    Safety Info

    RTECS

    PA8050000

    Hazard Class

    6.1

    Safety Statements

    S23-S24/25-S36/37

    HS Code

    2903120001

    WGK Germany

    2

    Packing Group

    III

    RIDADR

    UN 1593/1912

    Risk Statements

    R40

    Hazard Codes

    Xn

    Symbol

    GHS07, GHS08

    Signal Word

    Warning

    Hazard Declaration

    H315; H319; H335; H336; H351; H373

    Caution Statement

    P260; P280; P305 + P351 + P338

    SDS 1.0

    Expand

    SDS 1.0

    Collapse
    Download/Modify | Technical supported by XiXisys.com. For US version, EU version (23 languages) and more, please refer to xixisys.com/en/sds/search

    SAFETY DATA SHEETS

    According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

    Version: 1.0

    Creation Date: Aug 16, 2017

    Revision Date: Aug 16, 2017

    1.Identification

    1.1 GHS Product identifier

    Product name dichloromethane

    1.2 Other means of identification

    Product number -
    Other names Methane,dichloro

    1.3 Recommended use of the chemical and restrictions on use

    Identified uses For industry use only. Pesticides (chemicals used for killing pests, such as rodents, insects, or plants)
    Uses advised against no data available

    1.4 Supplier's details

    Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
    Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
    Xuhui District, Shanghai, China
    Telephone +86(21)64956998
    Fax +86(21)54365166

    1.5 Emergency phone number

    Emergency phone number +86-400-6021-666
    Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

    2.Hazard identification

    2.1 Classification of the substance or mixture

    Carcinogenicity, Category 2

    2.2 GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Warning

    Hazard statement(s)

    H351 Suspected of causing cancer

    Precautionary statement(s)
    Prevention

    P201 Obtain special instructions before use.

    P202 Do not handle until all safety precautions have been read and understood.

    P280 Wear protective gloves/protective clothing/eye protection/face protection.

    Response

    P308+P313 IF exposed or concerned: Get medical advice/ attention.

    Storage

    P405 Store locked up.

    Disposal

    P501 Dispose of contents/container to ...

    2.3 Other hazards which do not result in classification

    none

    3.Composition/information on ingredients

    3.1 Substances

    Chemical name Common names and synonyms CAS number EC number Concentration
    dichloromethane dichloromethane 75-09-2 none 100%

    4.First-aid measures

    4.1 Description of necessary first-aid measures

    General advice

    Consult a physician. Show this safety data sheet to the doctor in attendance.

    If inhaled

    Fresh air, rest. Artificial respiration may be needed. Refer immediately for medical attention.

    In case of skin contact

    Remove contaminated clothes. Rinse and then wash skin with water and soap.

    In case of eye contact

    First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

    If swallowed

    Rinse mouth. Do NOT induce vomiting. Refer for medical attention .

    4.2 Most important symptoms/effects, acute and delayed

    INHALATION: anesthetic effects, nausea and drunkenness. CONTACT WITH SKIN AND EYES: skin irritation, irritation of eyes and nose. (USCG, 1999)

    4.3 Indication of immediate medical attention and special treatment needed, if necessary

    Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Chlorinated fluorocarbons (CFCs) and related compounds/

    5.Fire-fighting measures

    5.1 Extinguishing media

    Suitable extinguishing media

    Use dry chemical, carbon dioxide, foam, or water spray. Use water spray to keep fire-exposed containers cool.

    5.2 Specific hazards arising from the chemical

    Special Hazards of Combustion Products: Dissociation products generated in a fire may be irritating or toxic. (USCG, 1999)

    5.3 Special protective actions for fire-fighters

    Wear self-contained breathing apparatus for firefighting if necessary.

    6.Accidental release measures

    6.1 Personal precautions, protective equipment and emergency procedures

    Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

    6.2 Environmental precautions

    Personal protection: self-contained breathing apparatus. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

    6.3 Methods and materials for containment and cleaning up

    Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.

    7.Handling and storage

    7.1 Precautions for safe handling

    Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

    7.2 Conditions for safe storage, including any incompatibilities

    Separated from strong oxidants, strong bases, metals and food and feedstuffs. See Chemical Dangers. Cool. Well closed. Ventilation along the floor.Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Heat sensitive. Store under inert gas.

    8.Exposure controls/personal protection

    8.1 Control parameters

    Occupational Exposure limit values

    NIOSH considers methylene chloride a potential occupational carcinogen.

    NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration.

    Biological limit values

    no data available

    8.2 Appropriate engineering controls

    Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

    8.3 Individual protection measures, such as personal protective equipment (PPE)

    Eye/face protection

    Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

    Skin protection

    Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

    Respiratory protection

    Wear dust mask when handling large quantities.

    Thermal hazards

    no data available

    9.Physical and chemical properties

    Physical state A colorless liquid with a sweet, penetrating, ether-like odor
    Colour Colorless liquid [Note: A gas above 104 degrees F]
    Odour Sweet, pleasant odor, like chloroform
    Melting point/ freezing point -97oC
    Boiling point or initial boiling point and boiling range 39.8-40°C(lit.)
    Flammability Combustible LiquidCombustible under specific conditions. Gives off irritating or toxic fumes (or gases) in a fire.
    Lower and upper explosion limit / flammability limit Lower flammable limit: 13% by volume; Upper flammable limit: 23% by volume
    Flash point 39-40oC
    Auto-ignition temperature 661.67°C
    Decomposition temperature no data available
    pH no data available
    Kinematic viscosity 0.437 mPa.s at 20°C
    Solubility In water:20 g/L (20 oC)
    Partition coefficient n-octanol/water (log value) log Kow = 1.25
    Vapour pressure 24.45 psi ( 55 °C)
    Density and/or relative density 1.325g/mLat 25°C(lit.)
    Relative vapour density 2.9 (vs air)
    Particle characteristics no data available

    10.Stability and reactivity

    10.1 Reactivity

    no data available

    10.2 Chemical stability

    In the absence of moisture at ordinary temp, dichloromethane is relatively stable when compared with its congeners, chloroform and carbon tetrachloride.

    10.3 Possibility of hazardous reactions

    It is flammable in the range of 12-19% in air but ignition is difficult.The vapour is heavier than air. As a result of flow, agitation, etc., electrostatic charges can be generated.DICHLOROMETHANE reacts vigorously with active metals such as lithium, sodium and potassium, and with strong bases such as potassium tert-butoxide. It is incompatible with strong oxidizers, strong caustics and chemically active metals such as aluminum or magnesium powders. The liquid will attack some forms of plastic, rubber and coatings. This compound reacts with sodium-potassium alloy, (potassium hydrogen + N-methyl-N-nitrosurea), nitrogen tetraoxide and liquid oxygen. It also reacts with titanium. On contact with water it corrodes iron, some stainless steels, copper and nickel. It is incompatible with alkali metals. It is incompatible with amines, zinc and alloys of aluminum, magnesium and zinc. This compound is liable to explode when mixed with dinitrogen pentaoxide or nitric acid. Mixtures of this compound in air with methanol vapor are flammable.

    10.4 Conditions to avoid

    no data available

    10.5 Incompatible materials

    Mixtures of /dinitrogen/ tetraoxide with ... dichloromethane ... are explosive when subjected to shock of 25 g TNT equiv or less.

    10.6 Hazardous decomposition products

    It can be decomposed by contact with hot surfaces and open flame, and then yield toxic fumes that are irritating and give warning of their presence. When heated to decomposition it emits highly toxic fumes of phosgene and /hydrogen chloride/.

    11.Toxicological information

    Acute toxicity

    • Oral: LD50 Rat oral 1600 mg/kg
    • Inhalation: LC50 Mouse inhalation 16000 ppm/7 hr plus 1 hr observation
    • Dermal: no data available

    Skin corrosion/irritation

    no data available

    Serious eye damage/irritation

    no data available

    Respiratory or skin sensitization

    no data available

    Germ cell mutagenicity

    no data available

    Carcinogenicity

    NTP: Reasonably anticipated to be a human carcinogen

    Reproductive toxicity

    No studies were located regarding developmental or reproductive effects in humans from inhalation or oral exposure. Animal studies have demonstrated that methylene chloride crosses the placental barrier, and minor skeletal variations and lowered fetal body weights have been noted.

    STOT-single exposure

    no data available

    STOT-repeated exposure

    no data available

    Aspiration hazard

    no data available

    12.Ecological information

    12.1 Toxicity

    • Toxicity to fish: LC50; Species: Danio rerio (Zebra danio); Conditions: freshwater, flow through, 23°C, pH 8.15; Concentration: 254000 ug/L for 48 hr /formulation
    • Toxicity to daphnia and other aquatic invertebrates: LC50; Species: Daphnia magna (Water flea) age < or =24 hr; Conditions: freshwater, static, 22°C, pH 7.4-9.4, dissolved oxygen 6.5-9.1 mg/L; Concentration: 310000 ug/L for 24 hr (95% confidence interval: 280000-340000 ug/L) /> or =80% purity
    • Toxicity to algae: no data available
    • Toxicity to microorganisms: no data available

    12.2 Persistence and degradability

    AEROBIC: Dichloromethane is reported to completely biodegrade under aerobic conditions with sewage seed or activated sludge between 6 hours to 7 days(1-5). Dichloromethane, present at 100 mg/L, reached 13% of its theoretical BOD in 4 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test (OECD 301C Method)(6). Using a respirometer test method, 49% of initial dichloromethane (10 mg/L) biodegraded using an adapted activated sludge inoculum(7). Using a Sapromat respirometer test method, nearly 100% of initial dichloromethane (660 mg/L) biodegraded using an adapted sewage inoculum(7). Dichloromethane was degraded at a concentration of 3.3 mg/L in the aqueous phase of natural sediment with a corresponding half-life of 10.9 days(8). Dichloromethane, at 50 mg/L, had 0% degradation in a Manometric respirometry test over a 28-day incubation period(9).

    12.3 Bioaccumulative potential

    Using carp (Cyprinus carpio) which were exposed over a 6-week period, a BCF range of 2.0-40 was determined for dichloromethane at initial concentrations of 25 and 250 ug/L(1). According to a classification scheme(2), this BCF range suggests bioconcentration in aquatic organisms is low to moderate(SRC).

    12.4 Mobility in soil

    Dichloromethane has reported experimentally derived Koc values of 28(1), 36(2), 48 and 8(3). According to a classification scheme(4), these Koc values suggest that dichloromethane is expected to have very high mobility in soil. Dichloromethane is adsorbed strongly to peat moss, less strongly to clay, only slightly to dolomite limestone, and not at all to sand(5).

    12.5 Other adverse effects

    no data available

    13.Disposal considerations

    13.1 Disposal methods

    Product

    The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

    Contaminated packaging

    Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

    14.Transport information

    14.1 UN Number

    ADR/RID: UN1593 IMDG: UN1593 IATA: UN1593

    14.2 UN Proper Shipping Name

    ADR/RID: DICHLOROMETHANE
    IMDG: DICHLOROMETHANE
    IATA: DICHLOROMETHANE

    14.3 Transport hazard class(es)

    ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1

    14.4 Packing group, if applicable

    ADR/RID: III IMDG: III IATA: III

    14.5 Environmental hazards

    ADR/RID: no IMDG: no IATA: no

    14.6 Special precautions for user

    no data available

    14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

    no data available

    15.Regulatory information

    15.1 Safety, health and environmental regulations specific for the product in question

    Chemical name Common names and synonyms CAS number EC number
    dichloromethane dichloromethane 75-09-2 none
    European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
    EC Inventory Listed.
    United States Toxic Substances Control Act (TSCA) Inventory Listed.
    China Catalog of Hazardous chemicals 2015 Listed.
    New Zealand Inventory of Chemicals (NZIoC) Listed.
    Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
    Vietnam National Chemical Inventory Listed.
    Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

    16.Other information

    Information on revision

    Creation Date Aug 16, 2017
    Revision Date Aug 16, 2017

    Abbreviations and acronyms

    • CAS: Chemical Abstracts Service
    • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
    • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
    • IMDG: International Maritime Dangerous Goods
    • IATA: International Air Transportation Association
    • TWA: Time Weighted Average
    • STEL: Short term exposure limit
    • LC50: Lethal Concentration 50%
    • LD50: Lethal Dose 50%
    • EC50: Effective Concentration 50%

    References

    • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
    • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
    • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
    • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
    • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
    • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
    • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
    • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
    • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

    Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.

    MSDS

    Expand
    1H NMR : 90 MHz in CDCl3Expand

    NMR Spectrum 1H NMR : 90 MHz in CDCl3

    Collapse

    C H2 Cl2 0.04 ml : 0.5 ml CDCl3
    dichloromethane

    75-09-2 NMR spectrum

    Assign. Shift(ppm)
    A 5.297

    IR : CCl4 solutionExpand
    Mass Expand
    Raman : 4880 A,150M,liquidExpand
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