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    lithium atom
    CAS No.: 7439-93-2 Formula: HLi Molecular Weight: 7.94894

    lithium atom

    CAS No.: 7439-93-2 Formula: HLi Molecular Weight: 7.94894
    Suppliers: All(0) China Suppliers(0) Price Available(0) Contractor(0)

    Basic Info

    Chemical Name lithium atom
    Synonyms

    LithiumingotN; lithium metal; Lithium rod; rolledfoil; Litium; Lithium ingot; Lithium foil; LITHIUM; lithium powder; Expand

    CAS No. 7439-93-2
    Molecular Formula HLi
    Molecular Weight 7.94894
    PSA 0.00000
    LogP 0.11250

    Numbering system

    UNII 9FN79X2M3F

    Properties

    Appearance & Physical State soft silver metal
    Density 0.534
    Boiling Point 1340oC
    Melting Point 180oC
    Water Solubility REACTS
    Stability Stability Stable, but reacts violently with water. Store under oil.
    Storage Condition water-free area

    Safety Info

    RTECS OJ5540000
    Hazard Class 4.3
    Safety Statements S43-S45-S8
    HS Code 2805190000
    WGK Germany 2
    Packing Group I
    RIDADR UN 1415
    Risk Statements R14/15; R34
    Hazard Codes C
    Supplemental Hazard Statements Reacts violently with water.
    Hazard Declaration H260; H314
    Symbol GHS02, GHS05
    Caution Statement P223; P231 + P232; P280; P305 + P351 + P338; P370 + P378; P422
    Signal Word Danger
    SDS 1.0 Expand

    SDS 1.0

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    SAFETY DATA SHEETS

    According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

    Version: 1.0

    Creation Date: Aug 16, 2017

    Revision Date: Aug 16, 2017

    1.Identification

    1.1 GHS Product identifier

    Product name lithium atom

    1.2 Other means of identification

    Product number -
    Other names rolledfoil

    1.3 Recommended use of the chemical and restrictions on use

    Identified uses For industry use only. Intermediates
    Uses advised against no data available

    1.4 Supplier's details

    Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
    Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
    Xuhui District, Shanghai, China
    Telephone +86(21)64956998
    Fax +86(21)54365166

    1.5 Emergency phone number

    Emergency phone number +86-400-6021-666
    Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

    2.Hazard identification

    2.1 Classification of the substance or mixture

    Substances and mixtures, which in contact with water, emit flammable gases, Category 1

    Skin corrosion, Category 1B

    2.2 GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Danger

    Hazard statement(s)

    H260 In contact with water releases flammable gases which may ignite spontaneously

    H314 Causes severe skin burns and eye damage

    Precautionary statement(s)
    Prevention

    P223 Do not allow contact with water.

    P231+P232 Handle and store contents under inert gas/.... Protect from moisture.

    P280 Wear protective gloves/protective clothing/eye protection/face protection.

    P260 Do not breathe dust/fume/gas/mist/vapours/spray.

    P264 Wash ... thoroughly after handling.

    Response

    P302+P335+P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].

    P370+P378 In case of fire: Use ... to extinguish.

    P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

    P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

    P363 Wash contaminated clothing before reuse.

    P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

    P310 Immediately call a POISON CENTER/doctor/…

    P321 Specific treatment (see ... on this label).

    P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

    Storage

    P402+P404 Store in a dry place. Store in a closed container.

    P405 Store locked up.

    Disposal

    P501 Dispose of contents/container to ...

    2.3 Other hazards which do not result in classification

    none

    3.Composition/information on ingredients

    3.1 Substances

    Chemical name Common names and synonyms CAS number EC number Concentration
    lithium atom lithium atom 7439-93-2 none 100%

    4.First-aid measures

    4.1 Description of necessary first-aid measures

    General advice

    Consult a physician. Show this safety data sheet to the doctor in attendance.

    If inhaled

    Fresh air, rest. Half-upright position. Refer for medical attention.

    In case of skin contact

    Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .

    In case of eye contact

    First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

    If swallowed

    Refer for medical attention . See Notes.

    4.2 Most important symptoms/effects, acute and delayed

    Contact with eyes causes caustic irritation or burn. Incontact with skin lithium reacts with body moisture to cause chemical burns: foil, ribbon, and wire react relatively slowly. (USCG, 1999)

    4.3 Indication of immediate medical attention and special treatment needed, if necessary

    Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during treatment ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Cover skin burns with dry sterile dressings after decontamination ... . /Lithium and related compounds/

    5.Fire-fighting measures

    5.1 Extinguishing media

    Suitable extinguishing media

    Extinguish lithium fires only with chemicals designed for this purpose.

    5.2 Specific hazards arising from the chemical

    Special Hazards of Combustion Products: Strong alkali fumes are formed in fire. Behavior in Fire: Molten lithium is quite easily ignited and is then difficult to extinguish. Hot or burning lithium will react with all gases except those of the helium-argon group. It also reacts violently with concrete, wood, asphalt, sand, asbestos; and in fact, nearly everything except metal. Do not apply water to adjacent fires. Hydrogen explosion may result. (USCG, 1999)

    5.3 Special protective actions for fire-fighters

    Wear self-contained breathing apparatus for firefighting if necessary.

    6.Accidental release measures

    6.1 Personal precautions, protective equipment and emergency procedures

    Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

    6.2 Environmental precautions

    Personal protection: complete protective clothing including self-contained breathing apparatus. Consult an expert! Do NOT wash away into sewer. Sweep spilled substance into covered dry, metallic, sealable containers. Carefully collect remainder. Then store and dispose of according to local regulations.

    6.3 Methods and materials for containment and cleaning up

    Eliminate all ignition sources. Keep water away from release. Shovel into suitable dry container.

    7.Handling and storage

    7.1 Precautions for safe handling

    Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

    7.2 Conditions for safe storage, including any incompatibilities

    Fireproof. Separated from strong oxidants, acids, halons and other incompatible materials. See Chemical Dangers. Dry. Keep under mineral oil.Store in a cool, dry, well-ventilated location. Separate from water.

    8.Exposure controls/personal protection

    8.1 Control parameters

    Occupational Exposure limit values

    no data available

    Biological limit values

    no data available

    8.2 Appropriate engineering controls

    Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

    8.3 Individual protection measures, such as personal protective equipment (PPE)

    Eye/face protection

    Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

    Skin protection

    Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

    Respiratory protection

    Wear dust mask when handling large quantities.

    Thermal hazards

    no data available

    9.Physical and chemical properties

    Physical state soft silver metal
    Colour Soft silvery-white metal
    Odour ODORLESS
    Melting point/ freezing point 180oC
    Boiling point or initial boiling point and boiling range 1342°C(lit.)
    Flammability Flammable. Many reactions may cause fire or explosion. Gives off irritating or toxic fumes (or gases) in a fire.
    Lower and upper explosion limit / flammability limit no data available
    Flash point no data available
    Auto-ignition temperature 178.89°C (USCG, 1999)
    Decomposition temperature no data available
    pH no data available
    Kinematic viscosity no data available
    Solubility In water:REACTS
    Partition coefficient n-octanol/water (log value) no data available
    Vapour pressure 7.90X10-11 Pa (5.92X10-13 mm Hg) at 400 K (127°C); 0.000489 Pa (3.67X10-6 mm Hg) at 600 K (327°C); 1.08 Pa (0.00810 mm Hg) at 800 K (524°C); 109 Pa (0.818 mm Hg) at 1000 K (727°C)
    Density and/or relative density 0.534g/mLat 25°C(lit.)
    Relative vapour density no data available
    Particle characteristics no data available

    10.Stability and reactivity

    10.1 Reactivity

    no data available

    10.2 Chemical stability

    Decomposes in water

    10.3 Possibility of hazardous reactions

    ... Flammable solid.Burns in air, oxygen, nitrogen, hydrogen, and carbon dioxide. The reactions can become extremely violent at higher temperatures. The disposition to ignite of surfaces of molten lithium exposed to any of these gases is increased by the presence of lithium oxides and nitrides. Lithium reacts avidly with water to generate gaseous hydrogen and a solution of lithium hydroxide (a caustic). Contact with halogenated hydrocarbons can produce extremely violent reactions, especially on impact [Haz. Chem. Data 1966]. Boron trifluoride reacts with incandescence when heated with lithium [Merck 11th ed. 1989]. Maleic anhydride decomposes explosively in the presence of lithium [Chemical Safety Data Sheet SD-88. 1962, Chem. Haz. Info. Series C-71. 1960]. Chlorine vapors and lithium react producing a luminous flame [Mellor 2, Supp. 1:380. 1956]. The product of the reaction between lithium and carbon monoxide, lithium carbonyl, detonates violently with water, igniting the gaseous products [Mellor 2, Supp. 2:84. 1961]. The reaction of lithium and ferrous sulfide starts around 260° C with subsequent rise in temperature to 950° C [Mellor 2, Supp. 2:80. 1961]. A truck, which was carrying lithium batteries, sodium dithionite and derivatives of cyanide, caught fire; multiple explosions occurred as the cargo was exposed to the air.

    10.4 Conditions to avoid

    no data available

    10.5 Incompatible materials

    Reacts with water forming lithium hydroxide and hydrogen. Keep under mineral oil or other liquid free from oxygen or water.

    10.6 Hazardous decomposition products

    Combustion may produce irritants and toxic gases.

    11.Toxicological information

    Acute toxicity

    • Oral: no data available
    • Inhalation: no data available
    • Dermal: no data available

    Skin corrosion/irritation

    no data available

    Serious eye damage/irritation

    no data available

    Respiratory or skin sensitization

    no data available

    Germ cell mutagenicity

    no data available

    Carcinogenicity

    no data available

    Reproductive toxicity

    no data available

    STOT-single exposure

    no data available

    STOT-repeated exposure

    no data available

    Aspiration hazard

    no data available

    12.Ecological information

    12.1 Toxicity

    • Toxicity to fish: no data available
    • Toxicity to daphnia and other aquatic invertebrates: no data available
    • Toxicity to algae: no data available
    • Toxicity to microorganisms: no data available

    12.2 Persistence and degradability

    no data available

    12.3 Bioaccumulative potential

    no data available

    12.4 Mobility in soil

    no data available

    12.5 Other adverse effects

    no data available

    13.Disposal considerations

    13.1 Disposal methods

    Product

    The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

    Contaminated packaging

    Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

    14.Transport information

    14.1 UN Number

    ADR/RID: UN1415 IMDG: UN1415 IATA: UN1415

    14.2 UN Proper Shipping Name

    ADR/RID: LITHIUM
    IMDG: LITHIUM
    IATA: LITHIUM

    14.3 Transport hazard class(es)

    ADR/RID: 4.3 IMDG: 4.3 IATA: 4.3

    14.4 Packing group, if applicable

    ADR/RID: III IMDG: III IATA: III

    14.5 Environmental hazards

    ADR/RID: no IMDG: no IATA: no

    14.6 Special precautions for user

    no data available

    14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

    no data available

    15.Regulatory information

    15.1 Safety, health and environmental regulations specific for the product in question

    Chemical name Common names and synonyms CAS number EC number
    lithium atom lithium atom 7439-93-2 none
    European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
    EC Inventory Listed.
    United States Toxic Substances Control Act (TSCA) Inventory Listed.
    China Catalog of Hazardous chemicals 2015 Listed.
    New Zealand Inventory of Chemicals (NZIoC) Listed.
    Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
    Vietnam National Chemical Inventory Listed.
    Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

    16.Other information

    Information on revision

    Creation Date Aug 16, 2017
    Revision Date Aug 16, 2017

    Abbreviations and acronyms

    • CAS: Chemical Abstracts Service
    • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
    • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
    • IMDG: International Maritime Dangerous Goods
    • IATA: International Air Transportation Association
    • TWA: Time Weighted Average
    • STEL: Short term exposure limit
    • LC50: Lethal Concentration 50%
    • LD50: Lethal Dose 50%
    • EC50: Effective Concentration 50%

    References

    • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
    • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
    • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
    • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
    • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
    • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
    • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
    • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
    • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

    Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
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